Below is a collection of classic photographic tones often produced in the darkroom. You can copy the tones with Photoshop Curves, or download Actions that allow you to automate toning in a single click. Here's a larger version of the picture in a gallery frame.
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Sepia #1 |
Sepia #2 |
Sepia #3 |
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Selenium |
Silver |
Cyanotype |
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Platinum |
Palladium |
Silver Gelatin |
To tone an image, first convert it to grayscale. You can use your favorite technique, or choose Image > Mode > Grayscale. Then convert back to RGB Color (Image > Mode > RGB Color). Then run the appropriate action to tone the image. If you're targeting a printer you may wish to introduce a white clip layer with the following curve to depress pure whites so they appear off-white giving the effect of toned paper stock.

Consider modifying Opacity, or the individual RGB curves, to suit your taste. For example, Palladium at 50% is especially nice. If the image needs more zing, add an S-shaped curve for a more dramatic high-contrast effect.